To prevent any discussion about what constitutes as face-melting that might interfere with drinking on Tuesdays, I am going to suggest that one of the top 5 best face-melters of all time is Slash.
What other man can pull off a hoop nose-ring and a top hat while smoking a cigarette and wailing sweet guitar riffs? Slash is the man.
If anyone should doubt that Slash is top 5 face-melters, check out his two guitar solos. One at 4 minutes and the other at 7 minutes.